ANSWERS
1. convert activity of 1.1E+3 curies to atoms-decaying/sec
? atoms/sec = 1.1E+3 Ci *[(3.7E+10 atoms/Ci)] = 4.07 E+13
convert amount of 1.00 g cobalt to atoms
? atoms = 1.00 g Co *[(6.02 E+23 atoms/60 g)] = 1.00 E+22
activity = k * (amount present), k = activity/amount
k = (4.07 E+13 atoms-decaying/sec)/(1.00 E+22 atoms)
= 4.056 E-9 sec-1
2. A fraction has two parts, a numerator and demoninator, to represent
two amounts of the same substance at different time points. Use
integrated form of first rate law...
k = ln(2)/(6.58 E+3 yrs) = 1.05 E-4 yrs-1
ln (Ao/A) = k t = (1.05 E-4 yrs-1)*(100 yrs)
= 1.05 E-2
(Ao/A) = e1.05 E-2 = 1.0106
The fraction remaining is current amount/starting amount = 1/1.0106
fraction remaining = 0.9895 or 98.95 % is still there after 100 years
3. Living things constantly replenish their C-14 content so as to have
a fixed activity of 15.3 counts/sec. Once expired, the C-14 activity
decreases with a half-life of 5720 years. (Ao/A) = (1/0.795)
k = ln(2)/5720 yrs = 1.21 E-4 yrs-1
ln(1.258) = (1.21 E-4 yrs-1)*time
time = 1900 years
4. This example has a mass loss due to a nuclear reaction. The products
have less mass than reactants. Convert mass loss to energy
using E = mc2.
Note units: c (velocity of light) = 3.0 E+8 meters/sec
force = mass * acceleration, and energy = force * distance
force (in Newtons) = kg * meters/sec2
energy (in Joules) = (kg * meters/sec2)*meters
Joules = kg * (meters/sec)2
mass loss of -0.0053 g/mol = 0.0053 E-3 kg/mol
E (in Joules) = (0.0053 E-3 kg)*(9.0 E+16 (meters/sec)2)
= 4.77 E+11 Joules
5. This example compares the mass of a Be-9 nucleus (containing
4 protons and 5 neutrons), with the mass of 4 individual protons and
5 individual neutrons. The mass difference is the bindng energy that
makes the 9 nucleons in the nucleus more stable than if they were
independent particles.
mass difference of -0.06248 g/mol = 0.06248 E-3 kg/mol
E (in Joules) = (0.06248 E-3 kg/mol)*((9.0 E+16 (meters/sec)2))
= 5.62 E+12 Joules
Binding Energy/nucleon = 5.62 E+12 Joules/9 = 6.25 E+8 kJ/mol/nucleon
Convert to energy units of million electron volts (MeV) and compare
with Figure 21.9 on page 1014.
? MeV = 6.25 E+8 kJ/mol/nu *[(1 MeV/1.60 E-16 kJ)*(1 mol/6.02 E+23)]
= 6.5 Mev
Find table 21.9 and note that Li-7 is at 5.8 MeV. Be-9 is the next
element, so our value of 6.5 MeV is just about where it should appear
in the table.
Send corrections, comments and suggestions to S. F. Pavkovic